ALCOHOL
INTRODUCTION ____Alcohol is a mobile, volatile fluid obtained by fermentation
of a sugar containingliquid. Its strength (concentration) can be further
increased by distillation.Alcohol, in general, is a family of organic chemical
compounds. Thus, there are variouskinds of alcohols in this alcohol family. It
includes Methanol (Methyl alcohol), Ethanol(Ethyl Alcohol), Propanol (Propyl
alcohol), Butanol (Butyl Alcohol) and so on. All thesealcohols are obtained on
replacing one Hydrogen (-H) atom by one Hydro-oxide (-OH)atom in its parent
chemical compound. For example: one Hydrogen atom in Methane(CH4) is replaced
by one Hydroxide atom to form Methanol (CH 3OH), one Hydrogenatom in Ethane
(C2H6) is replaced by one Hydroxide atom to form Ethanol (C 2H5OH) andso
on.Methyl alcohol (methanol) and Ethyl alcohol (ethanol) are the main alcohols
in thisfamily. Out of these two organic chemical compounds, Ethanol (C 2H5OH)
is potable andif sensibly consumed, is a beneficial alcohol. It has a faint but
pleasant ethereal smelland it is the alcohol that shall be dealt with. On the
other hand, Methanol is a powerfullydangerous poison if drunk. Its importance
is that it is widely used in industrial processes.
NOMENCLATURE____The
name Alcohol is derived from the Arabic word al-kohl. Kohl is a black, very
finestaining powder that is used cosmetically for staining the eyelids (and is
particularly used by ladies). Later, the name was applied to highly refined
chemical powders and essences and then to spirits produced by distillation and
rectification and now to any alcohol (alcoholic beverage) in general.ALCOHOLIC
BEVERAGE ____An alcoholic beverage is any potable (meaning drinkable) liquid
containing ethanol orethyl alcohol. In USA, Federal Government
during the Prohibition time defined that it 1
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may have as little as 0.5% to 95% alcohol by volume. However, social and
economicfactors, so also the taxation laws determine what are alcoholic
beverages. For example:Certain bitters and medicinal compounds contain as much
as 40% alcohol; even thenthey are not considered as alcoholic beverages and are
not taxed.HOW IS POTABLE ALCOHOL (ALCOHOLICBEVERAGE)
OBTAINED?_________________________All alcohols or alcoholic beverages are
obtained by a process called fermentation. It isconcentrated or increased in
strength by a process called Distillation. Both theseprocesses are discussed
below:FERMENTATIONFrench biologist Louis Pasteur (1822-95) explained
scientifically the principle offermentation, which is basic to the making of
all alcoholic beverages. When yeast isadded to any sugar containing liquid, it
reacts with sugar of the liquid to formalcohol and carbon dioxide. This
fundamental process is called fermentation. Ifthis liquid is not protected from
air, it is later converted to vinegar.Thus, fermentation is the breaking down
of organic substances (sugars particularlymaltose) by enzymes secreted by yeast
cells into mainly ethyl alcohol and carbondioxide gas. This is an exothermic
reaction i.e. heat is liberated during this reaction. Fermentable Sugars +
Yeast Enzymes → Alcohol + Carbon Dioxide Gas↑ + HeatScientifically describing, the enzymes secreted by yeast cells
react with one molecule ofsugar (maltose) to produce two molecules of
Ethanol and two molecules of CarbonDioxide Gas. Heat is generated during this
reaction.
C6H12O6
+ Yeast Enzmyes → 2CH3CH2OH + 2CO2↑+ Heat EnergyCarbon dioxide gas is usually but not always allowed to
escape. Here, the alcohol(ethanol)-a liquid remains behind in the original liquid,
which is then called afermented alcoholic beverage. These fermented alcoholic
beverages are preferablyrested, aged, matured and blended before being bottled
for sale. Fermented alcoholic..
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beverages have an alcoholic strength of generally 4% to 14% by volume. For example:Wines,
Mead, Pulque, Cider, Perry, Beers etc.A point, which is very important, is that
alcohol is obtained from ingredients containingsugar. For example: grape juice,
apple juice, pear juice etc. But, it can also be obtainedfrom ingredients such
as grain, cereals and potatoes, which have no sugar but have thepotential to
form sugar i.e. these cereals have a lot of starch present in them. Once
thestarch is converted into fermentable sugars, mainly maltose, yeast is
introduced andfermentation begins.Another point that requires mention is that
certain fermented alcoholic beverages likeBeer, Sake etc are brewed before they
are fermented. i.e. the mixture of grist (mashedcereals) and hot water is
brewed to extract flavour, taste and aroma before beingfermented. NAMES AND
BASE INGREDIENTS OF SOME FERMENTED ALCOHOLIC BEVERAGES Table, sparkling,
fortified and other wines - Grapes Cider - Apples Perry - Pears Mead - Honey
Pulque - Blue Agave or Maguey NAMES AND BASE INGREDIENTS OF SOME BREWED AND
FERMENTED ALCOHOLIC BEVERAGES Lagers, Ales and other beers - Grains Sake -
RiceDISTILLATIONThe process of separating one or more liquids by heating a
mixture of liquids iscalled distillation. It involves the sub-processes of
evaporation and condensation.The principle of distillation is that ethyl
alcohol vaporizes at a lower temperature (78.5° C) than water, which vaporizes
at 100 °C. So, when any fermented liquid is heated in an 3
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enclosed vessel called a still to a temperature of 78.5 °C, water remains in
the still andalcohol vaporizes which is channeled off and later condensed to
obtain a concentratedalcoholic liquid again. This concentrated alcoholic liquid
obtained after distillation iscalled a spirit-a kind of distilled alcoholic
beverage. This distilled alcoholic beverage(spirit) depending upon the method
of distillation (whether pot still or patent still) maybe rested, matured,
blended, and reduced in strength by adding de-ionized water andprobably given
colour enhancement before being bottled for sale. For example: Gin,Vodka,
Whisky etc. These fermented and distilled alcoholic beverages generally havean
alcoholic strength ranging from 37.5% to 57.5% by volume. But, some
distilledalcoholic beverages have an alcoholic strength as high as 75% by
volume.Important points that are notable in this process are as follows:(i) The
still is the apparataus, which allows the seperation of water and alcohol from
afermented liquid to be carried out (thus, a fermented liquid is a must for
distillation).Also, the quality of the final product depends a lot on the shape
and size of this still.(ii) Water is constantly vaporizing to some extent so
every distillation will contain water.(iii) The final product obtained after
distillation also consists of Congeners. Congenersare minor amounts of
aldehydes, ethers, esters, volatile acids, organic compounds andalso fusel oils
(higher alcohols like propanol, butanol etc) which give the product
itsdistinctive, individual character of taste, flavour and aroma. They come
along with thevaporizing process or by the extraction from the residue. These
are further enhanced asthe spirit ages in wood. For example: Aldehydes are
produced from a combination ofalcohols and air, and are particularly important
for the character of a spirit. Esters resultfrom a combination of acids and
alcohol and form a volatile substance that contributesto the aroma of a
spirit.There are two main methods of distillation by which distilled alcoholic
beverages (spirits)may be obtained:(i) POT STILL: It originated in the middle
ages and is associated with separate, slow andlow-temperature distillations. As
a result, the end product contains a good proportion ofcongeners and spirits
obtained by this method have to be matured for atleast two years bylaw. But,
usually it is matured longer than that. The entire heavy, highly flavoursome
spiritsare distilled by this method. For example: brandy, malt whisky, dark
rums, tequila and fineCalvados etc.The pot still is shaped like a giant onion
and consists of two parts: a still and a wormcondenser. The still is made of
copper because it is a good conductor of heat and alsoresists the effects of
acids, which are normally capable of dissolving metal. The copper wormcondenser
is connected to the still by a copper pipe. The worm passes through a jacket
offlowing cold water, which speeds up the condensation of the alcohol-rich
vapours. The potstill is time consuming and costly to operate. It needs to be
cooled, cleaned and refilled aftereach distillation, but it produces spirits of
remarkable individuality, quality and flavour.
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POT STILLWorking: The fermented liquid is placed in the still and slowly heated
over a naked flame.When the temperature reaches 78.5°C the alcoholic vapours
rise and pass through the wormto a condenser. Here the vapours are condensed
back into a liquid containing about 30%alcohol. This is re-distilled. The first
part of the distillate to emerge is known as the heads(foreshots) and contains
a high proportion of methanol. This is put to one side. The centralportion
(heart) of the distillation - the best part -- has an alcoholic strength of
about 80% andis channeled into the spirit receiver and ultimately into maturing
casks. The final part ofthe distillation, known as tails (feints or
after-shots), is weak in alcohol and contains thenauseating fusel oils and
other impurities. The heads and tails are sent back to be re-distilled and
refined. The new spirit (distilled alcoholic beverage) may be reduced
instrength by the addition of deionised water, which does not react with the
chemicalelements of the spirit. It is then well matured before bottling and
sending it for sale.(ii) PATENT STILL: The patent still or Coffey still is
named after its inventor AeneasCoffey-a Dublin excise officer. It
works on the principle of distillation by steam andproduces a continuous flow
of high strength alcohol. It uses rectification to make theend product as pure
and congener-free as possible. As a result, no maturing period isrequired by
law and the resultant product may be sold immediately it has beenproduced. It
is cheaper than the pot still to operate as it is lighter on fuel and does
notrequire the labour-intensive tasks of emptying, cleaning and refilling. The
patent still isassociated with all the light spirits such as vodka, gin, white
and light rums, grainwhiskies etc. 5
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PATENT STILLWorking: The patent still consists of two columns about 18 m high.
The analyzerseparate the constituent liquid parts while the rectifier condenses
the alcoholic vapours,raises the strength of and purifies the spirit. Each
column is sub-divided horizontally intochambers by perforated copper plates,
which have a drip pipe leading to the chamberunderneath. Both columns are
preheated by steam and the fermented liquid (also calledwash) enters at the top
of the rectifier through a pipe and gradually descends.By the time, the wash
reaches the bottom of the rectifier through the pipe; it is almost atboiling
point. It is then pumped into the analyser where it gradually makes its way 6
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downwards through perforated plates and bubble caps. As it descends, it is met
by acurrent of raw steam, which has been injected under pressure into the
bottom of theanalyser. On contact, the steam boils the wash and produces
alcoholic vapours that riseand are channelled by a pipe into the bottom of the
rectifier. The spent wash is removedfrom the bottom of the analyser.Meanwhile
inside the rectifier, the alcoholic vapours pass through a series of
perforatedplates. As they rise they meet the cold wash being carried down the
rectifier by thewash coil. Partial condensation takes place - the vapours
getting cooler and the wash,on its way to the analyser, getting hotter. When
the spirit vapours reach two-thirds ofthe way up in the rectifier, they hit a
cold spiral plate or water frame and precipitate.The first liquid to emerge -
the heads or foreshots - is removed and sent back to theanalyser because it is
pungent and needs further refining. The comparative pure spiritthat follows is
guided into a spirit receiver. The new spirit is then reduced in
alcoholicstrength by deionised water and matured for a short time before being
treatedaccording to style.NAMES AND BASE INGREDIENTS OF SOME DISTILLED
ALCOHOLIC BEVERAGES (SPIRITS) Cognac, Armagnac & other brandies - Grapes or
Wine Whisky - Grains or Beer Vodka, Kornbranntwein - Grains/Potatoes Light,
golden & dark Rums - Molasses (Sugarcane) Arrack - Dates, Palm Sap Mezcal,
Tequila - Blue Agave or Pulque Gin - Grains Aquavit - Grains, PotatoesNAMES AND
BASE INGREDIENTS OF SOME DISTILLED ALCOHOLIC BEVERAGES FROM FRUITS OTHER THAN
GRAPES (EAU DE VIE DES FRUITS) Calvados - Apples Slivovitz, Mirabelle, Quetsch
- Plums Kirsch - Cherries Eau de Vie de Poire - Pears Eau de Vie de Fraise -
Strawberries Eau de Vie de Framboise - Raspberries 7
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CLASSIFICATION AND TYPES (STYLES) OF ALCOHOLIC
BEVERAGES_______________________The main purpose of classification of Alcoholic
Beverages are two: (i) to provide thebase for accessing and collecting taxes by
the government and (ii) to protect theconsumer by making them understand the
differences between the products.The chart showing the classification and
different styles of alcoholic beverages is givenhereby:It shows that ALCOHOLIC
BEVERAGES are basically classified into FERMENTEDALCOHOLIC BEVERAGES and
DISTILLED ALCOHOLIC BEVERAGES dependingupon whether they are fermented or
distilled.These FERMENTED ALCOHOLIC BEVERAGES are classified into WINES,
MEAD,PULQUE, CIDER, PERRY, BEER, SAKE etc on the basis of base ingredients
used.WINES are further categoried into TABLE, SPARKLING, FORTIFIED,
AROMATISED,TONIC, VIN DOUX NATURELA, ORGANIC etc. on the basis of
theirnature/characteristics. All these WINE TYPES can also be classified (i) on
the basis oftheir colour into RED, PINK (ROSE) AND WHITE, (ii) on the basis of
their body intoHEAVY BODIED, MEDIUM BODIED OR LIGHT BODIED (especially red
wines) (iii) onthe basis of their degree of sweetness into DRY, MEDIUM DRY,
MEDIUM SWEET,SWEET etc (especially white wines). (iv) on the basis of alcohol
content into LOWALCOHOL WINES (max 1.2% by volume), DE-ALCOHOLISED WINES (max
0.5% byvolume) and ALCOHOL FREE OR NO ALCOHOL WINES (max 0.05% by volume).BEER
is classified on the basis of type of fermentation (bottom or top) into
mainlyLAGERS and ALES. However, there are other types like PORTER, PILSNER,
STOUT,GUINNESS, BOCK, STEAM etc.The DISTILLED ALCOHOLIC BEVERAGES are
classified into SPIRITS, LIQUEURS,BITTERS etc on the basis of their nature and
characteristics. SPIRITS are furthercategorised into WHISKY, GIN, RUM, VODKA,
TEQUILA, BRANDY, CALVADOS, EAUDE VIE DES FRUITS AND OTHERS depending upon the
base ingredient used.Further, famous WHISKIES are of four main types depending
upon the country of origin, base ingredient, method of manufacture etc: SCOTCH,
IRISH, AMERICAN ANDCANADIAN. GIN styles include FRUIT GINS, PLYMOUTH GIN,
LONDON DRY GIN,HOLLANDS GIN, MALT WINE etc. RUM styles are LIGHT RUM, GOLDEN
RUM ANDDARK RUM. TEQUILA styles include WHITE and GOLDEN (ANEJO). BRANDY typesinclude COGNAC, ARMAGNAC AND OTHERS. EAU DE VIE DES FRUITS
include EAU DE VIE DE POIRE, FRAISE, FRAMBOISE etc. LIQUEURS are further classified
into GENERIC LIQUEURS and BRANDED LIQUEURS.
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ALCOHOLIC STRENGTH_______The concentration of alcohol in an alcoholic beverage
is called its alcoholic strength. Alcoholic strength of any alcoholic beverage
is required to be measured so that the governments can tax them properly and
consumers might come to know about it, forcing them to drink sensibly. Various
methods are followed all over the world to determine the alcoholic strength of
an alcoholic beverage. Traditional or Primitive methods were followed before
the scientific methods were evolved. Both these kinds of various methods are
listed here: PRIMITIVE METHODS: It includes two methods:(a) Gunpowder: To test
alcoholic strength initially distillers mixed equal quantities of spirit and
gunpowder and applied a flame to it. If the mixture failed to ignite, the spirit
was too weak; if it exploded or burned too brightly, it was too strong, but if
it burned evenly with a mild blue flame, it was proved suitable and safe to
drink (potable).Hence, the word “proof”.(b) Clarke’s Float: In the seventeenth
century, Clarke invented a weighted float. Whenthis float was dropped into a
spirit, the depth to which it sank revealed the density of the liquor and the
alcoholic strength could be calculated from this. It was then able to calibrate
a particular strength as proof and any with a greater or lesser concentration of
alcohol was over proof’ or under proof’ respectively. MODERN SCIENTIFIC METHODS:
It includes four methods:(a) Sykes Hydrometer: In 1816, Sykes introduced Sykes
Hydrometer. Sykesdetermined that 100° was proof and that pure alcohol was 175°
(75° overproof). On thisscale, the figure for pure alcohol is I 3/4 times the
figure accorded to proof spirit. In other words, 100° proof equals 57.1%
alcohol and 42.9% water. The system also called British system became
traditional throughout the United Kingdom where spirits weresold
at a potable strength of 70° proof (30° underproof). So to convert the British
proofinto percent by volume of alcohol, simply multiply the proof by four and
divide by seven. 70 X 4 = 40% 7(b) Gay-Lussac System: Gay-Lussac (1778-1850)
invented this system, which was adopted throughout mainland Europe. In Gay-Lussac or GL system
0° is the absence of 11
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alcohol and 100° pure alcohol. Here, the alcoholic strength is measured at
15°C. Thus, degree equals percentage.© American System: The Americans
introduced their own system that was reasonably logical. They decided that proof
spirit was an exact balance of alcohol and water andthat pure alcohol is 200°
Proof. Each degree of proof equals one-half percent of alcohol.So, a spirit
marketed at 90° proof would contain 45% of alcohol by volume.(d) OIML Scale:
The Organisation Internationale de Metrologie Legale (OIML)expresses alcoholic
strength as a percentage by volume of alcohol (0% - 100%). It isvery similar to
the Gay-Lussac system except that OIML measures strength at 20°C.Thus,
Gay-Lussac system gives a slightly higher reading. The difference is almost
negligible except when deciding excise duty on very large quantities of drink.
Thissystem is followed now a days in the continent of Europe. APPROXIMATE ALCOHOLIC
STRENGTHS__________TYPE ALCOHOL BY VOLUME Alcohol free - maximum
0.05%De-alcoholised - maximum 0.5%Low alcohol - maximum 1.2%Cider - 4 – 6% but
‘specials’ up to 8%Beer - Light: 3 – 6%, Strong: 8 – 10%Table Wines - 8 – 15%,
usually 10 – 13%Sparkling Wines - 10 – 13%Fortified Wines - 16 – 22%Aromatised
Wines - 14 – 20%Vin doux Naturel - 15 – 18%Spirits - usually 37.5 – 45%, some
upto 57.5%Liqueurs - 17 – 55%BENEFITS OF ALCOHOL_________________________Some
of the benefits of alcohol are as follows:(i) Alcohol is not a direct cause of
any disease nor will it cure any disease. But, it is used medicinally for
treatment of certain physical conditions. It is world’s second oldest
disinfectant.(ii) Alcohol is good when drunk in moderation. It is a source of
nutrition and energy as it creates heat. 12
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(iii) As a food it is an appetizer, an accompaniment, an enhancer of flavors
and taste, aids digestion and sometimes used as correctives as well.(iv) It
accentuates sensory perception, sharpens memory and gives some protection tothe
heart and blood vessels by raising the level of good cholesterol.(v) It
depresses centers of anxiety, relieving tension and stress. Sometimes, it
exhilarates the spirit.
ABUSES
OF ALCOHOL__Alcohol must be treated very seriously and with respect. It is only
a problem to those who abuse it. Long time heavy drinking may lead to:(i)
serious illness including liver cirrhosis, hastening of age and deterioration
of nervous system.(ii) situations where it becomes an impediment in person’s
speed and quality of performance,(iii) the person becoming a danger to themselves
and others; especially when driving or operating machines.(iv) personality
changes in extreme cases. They become extremely unpleasant and unreliable.(v) a
person becoming unfit for work and a cause for embarrassment and burden totheir
families and friends. SAFE & SENSIBLE DRINKING_____________________Ingested
alcohol is readily and rapidly absorbed into the bloodstream. The liver burns up almost all this alcohol. Whatever is
remaining behind is discharged via urine or perspiration. The liver burns up
only one unit of alcohol per hour and as it being a living organ cannot cope up
with too much alcohol. To avoid any damage to health, the alcoholic intake
should be limited to 21 units a week for men and 14 units a week for women.
Care should be taken that this consumption should be spread throughout the week.
Usually,1 unit = 0.5 pint (28 cl) of ordinary beer or lager 1 glass (12.5cl) of
wine 1 measure (2.5cl) of spirit 1 glass (5cl) of sherry 1 measure (5cl) of vermouth
or other aperitif 13
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The limit for drivers is generally 80 mg of alcohol in 100 ml of blood. The
number of units required to reach this level varies between individuals but it
can be as little as 3units. After consumption, alcohol remains in the bloodstream
for up to 18 hours THINK IT OVER__!! !! !!